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Emissions and deposit properties from combustion of wood pellet with magnesium additives
Högskolan Dalarna, Akademin Industri och samhälle, Energi och miljöteknik.
Karlstads Universitet.
Högskolan Dalarna, Akademin Industri och samhälle, Materialteknik.
Visa övriga samt affilieringar
2013 (Engelska)Ingår i: Journal of Fuel Chemistry and Technology, ISSN 1872-5813, Vol. 41, nr 5, s. 530-539Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

This work studies the amount of gaseous and particleemissions and deposits on heat exchanger surfaces in a boiler fired withcommercially available pellets and with pellets primed with magnesium oxide andmagnesium hydroxide. The combustion experiments were performed on a residentialboiler of 20 kW. Substrates placed in the heat exchanger was analysed withSEM-EDX-mapping to evaluate the chemical composition of the deposits. Theresults show that particle emissions (PM 2.5) using the additives increased byabout 50% and the mass of the deposits in the flue gas heat exchanger (excludingloose fly ash) increased by about 25% compared to the combustion of pelletswithout additives. The amount of additives was found to be eight times higherthan the amount of the main alkali metals potassium (K) and sodium (Na) whichleads to the assumption that the additives were overdosed and therefore causedthe problems reported. The SEM analysis of the substrates placed in the fluegas heat exchanger indicate that the deposits of sodium (Na), potassium (K),chlorine (Cl) and sulphur (S) decrease using the additives. If this was due tothe expected chemical reactions or due to the loose fly ash covering thesubstrates after the test, could not be determined in this study.

Ort, förlag, år, upplaga, sidor
Elsevier, 2013. Vol. 41, nr 5, s. 530-539
Nyckelord [en]
softwood pellets; magnesium; additives; particle emissions; deposit formation
Nationell ämneskategori
Teknik och teknologier
Forskningsämne
Energi, skog och byggd miljö, SWX-Energi, Integrerade system för sol och biobränsle
Identifikatorer
URN: urn:nbn:se:du-12741DOI: 10.1016/S1872-5813(13)60029-8OAI: oai:DiVA.org:du-12741DiVA, id: diva2:638964
Tillgänglig från: 2013-08-05 Skapad: 2013-08-05 Senast uppdaterad: 2017-11-27Bibliografiskt granskad
Ingår i avhandling
1. Emissions from realistic operation of residential wood pellets heating systems
Öppna denna publikation i ny flik eller fönster >>Emissions from realistic operation of residential wood pellets heating systems
2015 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Emissions from residential combustion appliances vary significantly depending on the firing behaviours and combustion conditions, in addition to combustion technologies and fuel quality. Although wood pellet combustion in residential heating boilers is efficient, the combustion conditions during start-up and stop phases are not optimal and produce significantly high emissions such as carbon monoxide and hydrocarbon from incomplete combustion. The emissions from the start-up and stop phases of the pellet boilers are not fully taken into account in test methods for ecolabels which primarily focus on emissions during operation on full load and part load.

The objective of the thesis is to investigate the emission characteristics during realistic operation of residential wood pellet boilers in order to identify when the major part of the annual emissions occur. Emissions from four residential wood pellet boilers were measured and characterized for three operating phases (start-up, steady and stop). Emissions from realistic operation of combined solar and wood pellet heating systems was continuously measured to investigate the influence of start-up and stop phases on total annual emissions. Measured emission data from the pellet devices were used to build an emission model to predict the annual emission factors from the dynamic operation of the heating system using the simulation software TRNSYS.

Start-up emissions are found to vary with ignition type, supply of air and fuel, and time to complete the phase. Stop emissions are influenced by fan operation characteristics and the cleaning routine. Start-up and stop phases under realistic operation conditions contribute 80 – 95% of annual carbon monoxide (CO) emission, 60 – 90% total hydrocarbon (TOC), 10 – 20% of nitrogen oxides (NO), and 30 – 40% particles emissions. Annual emission factors from realistic operation of tested residential heating system with a top fed wood pelt boiler can be between 190 and 400 mg/MJ for the CO emissions, between 60 and 95 mg/MJ for the NO, between 6 and 25 mg/MJ for the TOC, between 30 and 116 mg/MJ for the particulate matter and between 2x10-13 /MJ and 4x10-13 /MJ for the number of particles. If the boiler has the cleaning sequence with compressed air such as in boiler B2, annual CO emission factor can be up to 550 mg/MJ. Average CO, TOC and particles emissions under realistic annual condition were greater than the limits values of two eco labels. These results highlight the importance of start-up and stop phases in annual emission factors (especially CO and TOC). Since a large or dominating part of the annual emissions in real operation arise from the start-up and stop sequences, test methods required by the ecolabels should take these emissions into account. In this way it will encourage the boiler manufacturers to minimize annual emissions.

The annual emissions of residential pellet heating system can be reduced by optimizing the number of start-ups of the pellet boiler. It is possible to reduce up to 85% of the number of start-ups by optimizing the system design and its controller such as switching of the boiler pump after it stops, using two temperature sensors for boiler ON/OFF control, optimizing of the positions of the connections to the storage tank, increasing the mixing valve temperature in the boiler circuit and decreasing the pump flow rate. For 85 % reduction of start-ups, 75 % of CO and TOC emission factors were reduced while 13% increase in NO and 15 % increase in particle emissions was observed.

Ort, förlag, år, upplaga, sidor
Västerås: Mälardalen University, 2015
Serie
Mälardalen University Press Dissertations, ISSN 1651-4238 ; 195
Nyckelord
Wood pellet, Heating, Combustion, boiler, stove, emissions, particulate matter
Nationell ämneskategori
Bioenergi
Forskningsämne
Energi, skog och byggd miljö, SWX-Energi, Integrerade system för sol och biobränsle
Identifikatorer
urn:nbn:se:du-20462 (URN)978-91-7485-246-2 (ISBN)
Disputation
2015-12-14, Clas Ohlson, Borlänge, 13:55 (Engelska)
Opponent
Handledare
Tillgänglig från: 2015-12-21 Skapad: 2015-12-18 Senast uppdaterad: 2016-03-16Bibliografiskt granskad

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